This study to prepare new bidentative ligand of imine 2, 4-dibromo-6-4-Cholro phenyl imino phenol by using 4-Chloro aniline with di-bromo salicylaldehyde and its metal complexes (M=CO (II) & Zn (II) have been synthesized. All the complexes ML ratio 1:2. They adopt octahedral geometry. The characterization of metal complexes have been confirmed by UV-Visible, FT-IR, elemental analysis like SEM, EDX, EPR and powdered XRD.